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Phys. Rev. 34, 1204–1211 (1929)

A Generalized Form of the New Statistics

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S. Chandrasekhar
Presidency College, Madras, India

Received 1 July 1929; published in the issue dated October 1929

Instead of assuming the probabilities of absorption and emission of atoms in a radiation field as equal to Baρ and A+Beρ (the well-known Einstein equations) Strum has in a recent paper assumed them to be respectively equal to Baρ+Caρ2+ and A+Beρ+Ceρ2+. This leads to a modification of Planck's law. It is shown in this paper that this assumption effectively amounts to replacing the new statistical law of interaction of Nordheim e.g. f(f*/A)f1*(f1*/A1) by the more general (f+af2+)(f*/A±af*2/A±)(f1+af12+)(f1*/A1±af1*2/A1±) where f, f1, f*, f1* are the distribution functions for the projectiles corresponding to the numbers of each before and after collision; A, A1 the number of cells respectively associated with them. On this basis a general H function defined by H=∫(f+af2+) log(f+af2+)∓(A±f±af2±)log(A±f±af2±) is considered. As a consequence of this we get a generalized distribution function given by the relation f+af2+bf3+=A/Cexp[c|v|2]∓1 If we take only two terms we get approximately J=A/Cec|v|2∓1-A2a/(Cec|v|2∓1)2=A/Cexp[c|v|2]∓1-A2a/(Cexp[c|v|2]∓1)2. By substituting the appropriate values for A in the cases corresponding to the photons and the atoms, we get Strum's modified radiation formula, and a new distribution function for a gas. Thus as a result of a generalized analysis of the H-theorem we get a new statistics the successive approximations of which are a more accurate statistics which includes Strum's formula, the statistics of Bose-Einstein, Fermi-Dirac, the classical statistics of Maxwell-Boltzmann. It is suggested that this new statistics may be of importance in the study of dense matter at high temperature.

© 1929 The American Physical Society

URL:
http://link.aps.org/doi/10.1103/PhysRev.34.1204
DOI:
10.1103/PhysRev.34.1204