Phys. Rev. A 62, 011201 (2000) [4 pages]

Thermal fluctuations of a metal atom on a C60 surface

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Philippe Dugourd, Rodolphe Antoine, Driss Rayane, Emmanuel Benichou, and Michel Broyer
Laboratoire de Spectrométrie Ionique et Moléculaire (UMR No. 5579), CNRS et Université Lyon I, Bâtiment 205, 43 Boulevard du 11 Novembre 1918, 69622 Villeurbanne Cedex, France

Rapid Communication Received 28 December 1999; published 12 June 2000

Fluctuations of a rubidium atom on the surface of a fullerene cage have been observed by measuring the electric susceptibility of isolated RbC60 molecules. The evolution of the susceptibility with the temperature is perfectly reproduced with a very simple statistical model of relaxation. The correlation time for these fluctuations and the activation energy (Ea=0.02 eV) for the motion of the alkali-metal atom on the C60 surface have been determined.


©2000 The American Physical Society

URL: http://link.aps.org/abstract/PRA/v62/e011201
DOI: 10.1103/PhysRevA.62.011201
PACS: 61.48.+c, 33.15.Kr, 36.40.Cg

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