Cooling and trapping of molecules in highly excited rotational states

Collisional relaxation of highly rotating hydrogen molecules is investigated as a function of energy. Calculations demonstrate that inelastic collisions are dramatically suppressed for specific rotational levels of the molecule as the energy is lowered due to the closing of quasiresonant rotation-vibration channels. It is predicted that a ³He buffer gas may be used to load these highly excited molecules into a trap without a significant loss of population. It is further predicted that evaporative cooling may be used to cool the “super rotors” to even lower temperatures.