Phys. Rev. A 9, 1103 - 1107 (1974)Semiclassical shape of satellite bands: Application to CsAr |
K. M. Sando
Department of Chemistry, University of Iowa, Iowa City, Iowa 52242
Received 4 September 1973
A term representing interference between classical paths is isolated from the previously derived equation for the semiclassical shape of satellite bands. A band shape quantitatively accurate in the adiabatic one-perturber approximation is given by addition of the classicalpath contributions to the interference term. Comparison is made to a quantum-mechanical calculation of a satellite band in the red wing of the self-broadened Lyman-α line of hydrogen and to an experimentally observed band in the blue wing of the cesium 8521-A resonance line perturbed by argon. The problem of inversion to determine a difference potential from the observed band shape is discussed.
©1974 The American Physical Society
URL: http://link.aps.org/abstract/PRA/v9/p1103
DOI: 10.1103/PhysRevA.9.1103
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