Phys. Rev. B 68, 195422 (2003) [10 pages]

Hole dynamics in a quantum-well state at Na/Cu(111)

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E. V. Chulkov1,2, J. Kliewer3, R. Berndt3, V. M. Silkin1, B. Hellsing4, S. Crampin5, and P. M. Echenique1,2
1Donostia International Physics Center (DIPC), Paseo de Manuel Lardizabal, 4, 20018 San Sebastián/Donostia, Basque Country, Spain
2Departamento de Física de Materiales and Centro Mixto CSIC-UPV/EHU, Facultad de Ciencias Químicas, UPV/EHU, Apartado Postal 1072, 20080 San Sebastián/Donostia, Basque Country, Spain
3Institut für Experimentelle und Angewandte Physik, Christian-Albrechts-Universität zu Kiel, D-24098 Kiel, Germany
4Experimental Physics, Chalmers University of Technology and Göteborg University, S-412 96 Göteborg, Sweden
5Department of Physics, University of Bath, Bath BA2 7AY, United Kingdom

Received 15 April 2003; published 26 November 2003

Theoretical calculations and scanning-tunneling spectroscopy measurements of the hole lifetime broadening, τ-1, in a quantum-well state for 0.95 and 1.0 monolayers of Na on Cu(111) are reported. A model potential is proposed for calculating quantum-well states in a monolayer on metal surfaces. The inelastic electron-electron contribution, τe-e-1, is evaluated within the GW approximation by using eigenfunctions and eigenenergies obtained with this model potential. The electron-phonon contribution, τe-ph-1, is computed by employing Debye and Einstein models as well as a first-principle ultrasoft pseudopotential method. The obtained theoretical results are in excellent agreement with experimental data, both showing a surprisingly large difference in the lifetime broadening for 0.95 and 1.0 monolayers which is attributed mostly to changes in the electronic structure.


©2003 The American Physical Society

URL: http://link.aps.org/doi/10.1103/PhysRevB.68.195422
DOI: 10.1103/PhysRevB.68.195422
PACS: 73.20.At, 71.45.Gm, 73.50.Gr, 78.47.+p

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