Phys. Rev. B 68, 033310 (2003) [4 pages]

Surface vibrations of diamond C(001)(2×1)

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S. Thachepan, H. Okuyama, T. Aruga, and M. Nishijima
Department of Chemistry, Graduate School of Science, Kyoto University, Kyoto 606-8502, Japan

T. Ando
National Institute for Material Sciences (NIMS), 1-1 Namiki, Tsukuba, Ibaraki 305-0044, Japan

S. Baǧcı and H. M. Tütüncü
Sakarya Üniversitesi, Fen-Edebiyat Fakültesi, Fizik Bölümü, Adapazarı, Turkey

G. P. Srivastava
School of Physics, University of Exeter, Stocker Road, Exeter EX4 4QL, United Kingdom

Received 4 March 2003; published 17 July 2003

Surface vibrations of diamond C(001)(2×1) have been studied by means of electron energy loss spectroscopy as well as first-principles theoretical calculations. Several vibrational modes are newly resolved. Outside the bulk phonon band, we observe a surface-derived mode at 172 meV, which is assigned as the dimer stretching mode as predicted by theoretical results. The other losses are in resonance with the bulk phonon band, and thus, they cannot be assigned as pure surface or bulk modes. The dispersions of the loss peaks are measured along the high-symmetry directions of the surface Brillouin zone, where we find nearly localized character of the vibrations along the surface.


©2003 The American Physical Society

URL: http://link.aps.org/abstract/PRB/v68/e033310
DOI: 10.1103/PhysRevB.68.033310
PACS: 68.35.Ja, 68.49.Uv, 79.20.Uv

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